MS19-P07 Environmental-friendly materials by alkali activation Serena Chiara Tarantino (Department of Earth and Environmental Sciences, University of Pavia, Pavia, Italy) Roberta Occhipinti (Department of Earth and Environmental Sciences, University of Pavia, Pavia, Italy) Gennaro Ventruti (Department of Earth and Geo-environmental Sciences, University of Bari, Bari, Italy) Michele Zema (Department of Earth and Environmental Sciences, University of Pavia, Pavia, Italy)email: serenachiara.tarantino@unipv.itAlkali activation is the chemical process through which an aluminosilicate powder (referred to as the precursor) interact with a strongly alkaline medium (the activator) to yield ceramic-like materials with good binding properties. The process occurs at room temperature starting from waste or industrial by-products, allowing for a significant reduction of emissions of greenhouse gases. Nowadays, Alkali Activated Materials (AAMs) have emerged as novel engineering materials with potential use in many application fields, in particular as environmental-friendly alternative to traditional construction materials. AAMs exhibit properties, which include formability comparable to epoxies, high temperature stability, chemical resistance comparable to ceramic oxides and compressive strength superior to concrete. Moreover, they show adsorptive properties towards metal cations, wastewater pollutants and CO2. Tailoring the properties of AAMs for specific applications requires full control on synthesis conditions and understanding of the structural and microstructural features of the final product.
In a recent work from our group, the feasibility of using sulphate-bearing kaolin for alkali activation has been assessed [1]. Alunite, KAl3(SO4)2(OH)6, which is present in the kaolin, hinders the use of these clays in the ceramic industry due to the release of SOx at HT. Nonetheless, it is a potential source of potassium and aluminium. AAMs obtained at temperature below desulphation show high thermal stability and compressive strength as high as ca. 80 MPa. Thenardite, Na2SO4, deriving from the dissolution of alunite, was observed in the final products. Nonetheless, sulphate is still present in the samples after leaching. In order to identify the possible non-soluble sulphate-bearing phases and evaluate the possibility of sulphate uptake by the gel itself, zeolitisation of kaolin was carried out under molten conditions [2] in the absence or presence of sulphate.
Kaolin-alunite mixtures were melted with NaOH at 550°C, incubated in vessels with distilled water, and resulting powders characterized by Rietveld refinements of XRPD patterns, FT-IR and SEM-EDS. Zeolites Y and A crystallize in sulphate-free mixtures, as expected, while sulphate-bearing CAN is the main reaction product of all alunite-containing batches. Therefore, sulphate ion could drive the nucleation and precipitation of CAN-type zeolites at room pressure, analogously to CO3-, NO3-, and SO32- [3]. These findings suggest that sulphate may have the same effect also in alkali activation process. This hypothesis is supported by preliminary 29Si and 27Al NMR data, indicating cancrinite as one of the candidate phases for trapping sulphur in AAMs.

[1] Gasparini, E., Tarantino, S.C., Conti, M., Biesuz, R., Ghigna, P., Auricchio, F., Riccardi, M.P., Zema M. (2015) Applied Clay Science, 114, 530-539.

[2] Park, M., Choi, C.L., Lim, W.T., Kim, M.C., Choi, J., Heo, N.H. (2000) Microporous and Mesoporous Materials, 37, 81-89.

[3] Hackbarth, K., Gesing, T.M., Fechtelkord, M., Stief, F., Buhl, J.-C. (1999) Microporous and Mesoporous Materials, 30, 347-358.
Keywords: Alkali Activated Materials, framework silicate, zeolite