MS16-P19 Influence of Microstructure on Symmetry Determination of Piezoceramics Manuel Hinterstein (Institute for Applied Materials, Karlsruhe Institute of Technology, Karlsruhe, Germany) Henry E. Mgbemere (Department of Metallurgical and Materials Engineering, University of Lagos, Lagos, Nigeria) Markus Hoelzel (Heinz Maier-Leibnitz Zentrum, Technische Universit√§t M√ľnchen, Garching, Germany) Esmaeil Adabifiroozjaei (School of Materials Science and Engineering, UNSW Australia, Sydney, Australia) Charles Sorrell (School of Materials Science and Engineering, UNSW Australia, Sydney, Australia) Mark Hoffman (School of Materials Science and Engineering, UNSW Australia, Sydney, Australia)email:

Frequently symmetry determination in studies is based on the discussion of agreement factors or the quality of the refinements, rather than on the basis of physical arguments. Especially in the field of piezoceramics this can be observed in the discussion whether monoclinic symmetry can be observed or not.

In this study we could show with temperature-dependent high-resolution X-ray and neutron diffraction that based on agreement factors alone the physical origin of observations cannot be revealed. Only in combination with additional electron microscopy and electron probe microanalysis we could elucidate that a segregation of substituents results in a complex reflection splitting and phase coexistence that can be misinterpreted as monoclinic symmetry. This single-phase monoclinic Pm model is able to perfectly reproduce the diffraction patterns and is known from literature [1,2]. A model with phase coexistence of two classical orthorhombic Amm2 phases can reproduce the diffraction data with equal accuracy.

This demonstrates the need of comprehensive analyses with complementary methods to cover a broad range of length scales as well as considering both average and local structure. The conclusions drawn from this work will have an impact on a broad range of research areas where inhomogeneities cannot be ruled out. The underlying mechanisms of the extraordinary properties of some functional materials originate not just in their structures but also their complex microstructures. Consequently, knowledge of both features of materials may be essential for the exploitation and development of their functionalities as well as improvement of material properties.


[1] H. E. Mgbemere, M. Hinterstein, and G. A. Schneider, J. Eur. Ceram. Soc. 32, 4341 (2012).

[2] L. Liu, X. Ma, M. Knapp, H. Ehrenberg, B. Peng, L. Fang, and M. Hinterstein, Europhys. Lett. 118, 47001 (2017).
Keywords: piezoelectric,ceramics, ferroelectricity